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HALON 1211
MATERIAL SAFETY DATA SHEET
Prepared to U.S. OSHA, CMA, ANSI, Canadian WHMIS Standards and European EU Standards SECTION 1. PRODUCT IDENTIFICATION
PRODUCT NAME: HALON 1211
CHEMICAL NAME: BROMOCHLORODIFLUOROMETHANE
SYNONYMS: R 12B1; BCF; Chlorodifluoromonobromomethane; Flugex 12B1; Fluorocarbon 1211; Freon 12B1;
Halon 1211; Methane, bromochlorodifluoro- PRODUCT USE: Fire Extinguishing Material
MANUFACTURER:
ADDRESS:
H3R Aviation, Inc.
800/249-4289 (8:00 a.m. to 4:30 p.m. PST) WEB SITE:
EMERGENCY PHONE:
CHEMTREC: 1-800-424-9300 (U.S./Canada/Puerto Rico) [24-hours] CHEMTREC: +1-703-527-3887 (Outside North America) [24-hours] DATE OF PREPARATION: September 21, 2006
DATE OF REVSION: August 18, 2009
NOTE: ALL United States Occupational Safety and Health Administration Standard (29 CFR 1910.1200), U.S. State equivalent Standards, Canadian WHMIS [Controlled Products
Regulations], and European Union [Regulation (EC) 1907/2006 Annex II] required information is included in appropriate sections based on the U.S. ANSI Z400.1-2004 format. This
product has been classified in accordance with the hazard criteria of the countries listed above.
SECTION 3. HAZARD IDENTIFICATION
EMERGENCY OVERVIEW: Product Description: Halon 1211 is a colorless, liquefied gas, with a sweet odor, shipped under
pressure. Health Hazards: The main acute health hazard associated with releases of this gas is asphyxiation by displacement of
oxygen. This gas is heavier than air and will sink into low areas, creating an asphyxiation hazard. The main chronic health hazard
associated with releases of this gas is possible adverse effects to the central nervous system and possible cardiac sensitization
and arrhythmias. Chronic skin exposure may cause dermatitis. Flammability Hazards: This gas is not flammable. Reactivity
Hazards: This gas is not reactive. Environmental Hazards: Release of this product to the environment is not expected to cause
environmental harm. Emergency Response Considerations: Emergency responders must wear the proper personal protective
equipment suitable for the situation to which they are responding. WARNING—If rescue personnel need to enter an area suspected
of having a low level of Oxygen, they should be equipped with Self-Contained Breathing Apparatus (SCBA) and appropriate
personal protective equipment.
EU LABELING/CLASSIFICATION: Currently, there is no classification applicable per Directives 67/548/EEC and
1999/45/EC and subsequent Directives.
EU Risk Phrases: Not Applicable
EU Safety Phrases: Not Applicable
SECTION 3. COMPOSITION and INFORMATION ON INGREDIENTS
Chemical Name
Chemical
EU Classification For Components
Composition
HAZARD CLASSIFICATION: Not applicable RISK PHRASES: Not Applicable See Section 15 (Regulatory Information) for full EU Risk and Safety Phrase information. SECTION 4. FIRST AID MEASURES
EYE CONTACT: If mechanical injury occurs, cover eye with bandage and seek appropriate medical attention.
INGESTION: Ingestion is an unlikely route of exposure for this gas.
INHALATION: Remove victim(s) to fresh air, as quickly as possible. Trained personnel should administer supplemental oxygen
and/or cardio-pulmonary resuscitation, if necessary.
SKIN CONTACT: If skin contact causes adverse effects, begin decontamination with warm, running water. Minimum flushing is
for 20 minutes. Remove exposed or contaminated clothing, taking care not to contaminate eyes. Victim must seek immediate
medical attention if any adverse effect occurs. In case of frostbite, place the frostbitten part in warm water. DO NOT USE HOT
WATER. If warm water is not available, or is impractical to use, wrap the affected parts gently in blankets. Alternatively, if the
fingers or hands are frostbitten, place the affected area in the armpit. Encourage victim to gently exercise the affected part while
being warmed. Seek immediate medical attention.
MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: None are anticipated.
H3R Clean Agent Specialists, Inc.
Halon 1211
Page 1 of 11
HALON 1211
SECTION 4. FIRST AID MEASURES (Continued)
NOTES TO PHYSICIANS: Administer oxygen, if necessary, and treat symptoms. This gas is an asphyxiant and can induce
cardiac muscle sensitization to circulating epinephrine-like compounds. Do NOT give adrenalin or similar sympathomimetic
drugs. Do NOT allow victim to exercise until 24 hours following specific exposures. Freeze burns of mucosal tissue can
develop following specific exposures.
SECTION 5. FIRE FIGHTING MEASURES
FLASH POINT: Not Applicable
NFPA RATING
AUTOIGNITION: Not Applicable
FLAMMABILITY
FLAMMABLE RANGE: Not Applicable
EXTINGUISHING MEDIA: This is a non-flammable gas; use fire-extinguishing
media appropriate for the surrounding materials.
SPECIAL FIRE-FIGHTING PROCEDURES: Non-flammable gas. Use
extinguishing media appropriate for surrounding fire.
INSTABILITY
UNUSUAL FIRE AND EXPLOSION HAZARDS: This gas does not burn;
however, containers, when involved in fire, may rupture or burst in the heat of the
fire. Most cylinders have a pressure release device, which will vent contents if the cylinder is exposed to high temperatures. This gas is heavier than air, creating an asphyxiation hazard in low areas. EXPLOSION SENSITIVITY TO MECHANICAL IMPACT: Not sensitive.
Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate
EXPLOSION SENSITIVITY TO STATIC DISCHARGE: Not sensitive.
3 = Serious 4 = Severe
HAZARDOUS COMBUSTION PRODUCTS: Combustion or decomposition products above 481.7°C (900°F) include
hydrogen bromide, hydrogen chloride, hydrogen fluoride, free halogens, and small amounts of carbonyl halides. These by-
products have a sharp irritating odor and are dangerous even in low concentrations and in sufficient concentrations can result
in personal injury or death.
SECTION 6. ACCIDENTAL RELEASE MEASURES
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: All release to the environment should be
avoided as this material has an ozone depletion potential and a global warming potential.
In the event of a release of this product, operator should close the gas source if possible to do so safely. Evacuate area in the
event of a significant release. Only trained personnel, wearing Self-Contained Breathing Apparatus (SCBA) should re-enter a
contaminated area if oxygen levels are below 19.5% or unknown.
If leak is in user’s gas handling equipment or system, close cylinder valve, and safely vent high pressure before attempting repairs.
If leak is from the cylinder, cylinder valve or the valve pressure relief device (PRD), contact your supplier.
Detection systems should be available to monitor for level of oxygen. The level of oxygen should above 19.5% before personnel
can be allowed in the area without SCBA.
SECTION 7. HANDLING AND STORAGE
STORAGE: Cylinders should be stored upright (with valve protection caps or plugs in place) and firmly secured to prevent falling
or being knocked over. Cylinders should be stored in dry, well-ventilated areas. Protect from salt or other corrosive materials.
Storage should be away from heavily traveled areas, walkways, elevators, platform edges or other objects or situations that could
damage the cylinder wall. Do not store in a manner that will block emergency exits, fire extinguishers or other safety equipment.
Do not allow storage temperature to exceed 125°F (52°C). Use a first-in, first-out inventory system to prevent full containers from
being stored for long periods of time. Store empty cylinders away from full cylinders. NOTE: Use only DOT or ASME code
cylinders designed for compressed gas storage. Cylinders must not be recharged except by or with the consent of owner.
HANDLING: Releases of Halon 1211 can create an oxygen-deficient atmosphere. Be aware of any signs of dizziness or
fatigue; exposures to fatal concentrations of Helium-3 could occur without any significant warning symptoms, due to oxygen-
deficiency. Wearing contact lenses is not recommended when handling this gas.
Cylinder valves should be inspected regularly for physical damage or corrosion (apparent by discoloration or rust). Care should be
taken to inspect the following valve locations for corrosion: neck (where valve inserts into cylinder); bonnet nut (where handle
attaches to valve body). Close valve after each use and when empty.
Do not drag, roll, slide or drop cylinder. Use a suitable hand truck designed for cylinder movement. Never attempt to lift a cylinder
by its cap. Secure cylinders at all times while in use. Use a pressure regulator to safely discharge product from cylinder. Use a
check valve to prevent reverse flow into cylinder. Once cylinder has been connected to properly purged process, open cylinder
valve slowly and carefully. If user experiences any difficulty operating cylinder valve, discontinue use and contact supplier. Never
insert an object (e.g., wrench, screwdriver, etc.) into valve cap openings; doing so may damage valve, causing a leak to occur.
Use an adjustable strap-wrench to remove over-tight or rusted caps.
Do not heat cylinders by any means to increase the discharge rate of product from the cylinder. Never apply flame or localized
heat directly to any part of the cylinder. Cylinders should not be artificially cooled as certain types of steel undergo property
changes when cryogenically cooled, thus making the cylinder unstable.
PRODUCT USE: This product is used as a fire-extinguishing agent, refrigerant gas and as a cleaning agent.
PROTECTIVE PRACTICES DURING MAINTENANCE OF CONTAMINATED EQUIPMENT: Follow practices
indicated in Section 6 (Accidental Release Measures). Relieve pressure before attempting repairs.
H3R Clean Agent Specialists, Inc.
Halon 1211
Page 2 of 11
HALON 1211
SECTION 7. HANDLING AND STORAGE (Continued)
SPECIAL PRECAUTIONS: Be aware of any signs of dizziness or fatigue; exposures to fatal concentrations of this gas could
occur without any significant warning symptoms. All work operations should be monitored in such a way that emergency personnel
can be immediately contacted in the event of a release. Always store and handle compressed gas cylinders in accordance with
Compressed Gas Association, Inc. (telephone 703-412-0900) pamphlet CGA P-1, Safe Handling of Compressed Gases in
Containers. Local regulations may require specific equipment for storage and use.
SECTION 8. EXPOSURE CONTROLS / PERSONAL PROTECTION
VENTILATION AND ENGINEERING CONTROLS: Forced ventilation systems for the general work area should be
provided. If appropriate, install automatic monitoring equipment to detect the level of oxygen.
EXPOSURE LIMITS:
Chemical Name
OSHA PELs
ACGIH TLVs
NIOSH RELs
NIOSH IDLH
AIHA WEELs
NE = Not Established
The following information on appropriate Personal Protective Equipment is provided to assist employers in complying with
OSHA regulations found in 29 CFR Subpart I (beginning at 1910.132), equivalent standards of Canada (including CSA
Standard Z94.4-02 and CSA Standard Z94.3-07), or standards of EU member states (including EN 529:2005 for respiratory
PPE, CEN/TR 15419:2006 for hand protection, and CR 13464:1999 for face/eye protection). Please reference applicable
regulations and standards for relevant details.
INTERNATIONAL EXPOSURE LIMITS: Currently, the following international exposure limits are in place for Halon 1211
(specific country limits may become available or change-consult individual countries for most current information).
BROMOCHLORODIFLUOROMETHANE:
Russia: STEL = 1000 mg/m3, JAN 1993
The following information on appropriate Personal Protective Equipment is provided to assist employers in complying with OSHA regulations found in 29 CFR Subpart I (beginning at 1910.132) or equivalent standard of Canada, or standards of EU member states (including EN 149 for respiratory PPE, and EN 166 for face/eye protection). Please reference applicable regulations and standards for relevant details. RESPIRATORY PROTECTION: Maintain oxygen levels above 19.5% in the workplace. Use supplied air respiratory
protection if oxygen level is below 19.5%, or during emergency response to a release of this product. If respiratory protection is
required, follow the requirements of the U.S. Federal OSHA Respiratory Protection Standard (29 CFR 1910.134), equivalent U.S.
State standards, Canadian CSA Standard Z94.4-02, or European Standard EN 529:2005. Oxygen levels below 19.5% are
considered IDLH by OSHA. In such atmospheres, use of a full-facepiece pressure/demand SCBA or a full facepiece, SAR with
auxiliary self-contained air supply is required under OSHA’s Respiratory Protection Standard (1910.134-1998).
EYE PROTECTION: Use approved safety goggles or safety glasses, when cylinders are not closed and capped. Be aware
that particles or objects propelled by high pressure gas can fly significant distances. Eyewear should be as described in U.S.
OSHA 29 CFR 1910.133, European Standard CR 13464:1999, or Canadian CSA Standard Z94.3-07.
HAND PROTECTION: Work (such as leather) gloves are recommended when handling cylinders of this gas. Wear gloves
appropriate to the specific operation for which this gas is used. Use triple gloves for spill response. If necessary, refer to U U.S.
OSHA 29 CFR 1910.138 appropriate Standards of Canada, or the European Standard CEN/TR 15419:2006.
OTHER PROTECTIVE EQUIPMENT: Use body protection appropriate for task. Safety shoes are recommended when
handling cylinders. Information on general protective measures can be found in U.S. OSHA 29 CFR 1910.136. OSHA Technical
Manual (Section VII: Personal Protective Equipment), appropriate Standards of Canada, or the European Standard CEN/TR
15419:2006. If a hazard of injury to the feet exists due to falling objects, rolling objects, where objects may pierce the soles of the
feet or where employee’s feet may be exposed to electrical hazards, use foot protection, as described in U.S. OSHA 29 CFR
1910.136 and the Canadian CSA Standard Z195-02, Protective Footwear.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Halon 1211
Molecular Weight
Boiling Point @ 1 atm
Freezing/Melting Point @ 1 atm
Specific Gravity [Relative Density] (air = 1)
Solubility in Water :
Vapor Pressure:
Vapor Density (air=1)
Odor Threshold
APPEARANCE, ODOR AND STATE: Colorless gas with a sweet odor.
WARNING PROPERTIES FOR THIS GAS: The odor may be a warning of a release. In terms of leak detection, fittings and
joints can be painted with a soap solution to detect leaks, which will be indicated by a bubble formation.
H3R Clean Agent Specialists, Inc.
Halon 1211
Page 3 of 11
HALON 1211
SECTION 10. STABILITY AND REACTIVITY
CHEMICAL STABILITY: Stable.
CONDITIONS TO AVOID: Cylinders should not be exposed to temperatures in excess of 125°F (52°C).
MATERIALS WITH WHICH GAS IS INCOMPATIBLE: Metal halides. Contact with acids can evolve highly toxic hydrogen
chloride.
REACTIVITY:
A) HAZARDOUS DECOMPOSITION PRODUCTS: Combustion or decomposition products above 900°F include
hydrogen bromide, hydrogen chloride, hydrogen fluoride, free halogens, and small amounts of carbonyl halides. These by-
products have a sharp irritating odor.
B) HAZARDOUS POLYMERIZATION: Will not occur.
SECTION 11. TOXICOLOGICAL INFORMATION
ROUTES OF ENTRY, SYMPTOMS OF ACUTE EXPOSURE:
WARNING-If rescue personnel need to enter an area in which a release HAZARDOUS MATERIAL IDENTIFICATION SYSTEM
of Halon 1211 has occurred, they should be equipped with Self-Contained Breathing Apparatus (SCBA) and appropriate personal protective equipment. High concentration of this gas will create an oxygen-deficient atmosphere, creating the risk of asphyxiation. HEALTH HAZARD
EYE CONTACT: Release of a high-pressure gas may result in
airborne objects.
INGESTION: Ingestion of this gas is not a likely route of industrial
exposure.
FLAMMABILITY HAZARD (RED) 0
INHALATION: Inhalation of high concentrations of this gas may
lead to heart arrhythmias. High concentrations of this gas can cause
an oxygen-deficient environment. Individuals breathing such an
atmosphere may experience symptoms which include headaches,
ringing in ears, dizziness, drowsiness, unconsciousness, nausea,
PHYSICAL HAZARD (YELLOW) 0
vomiting, and depression of all the senses. The skin of a victim may have a blue color. Under some circumstances of over-exposure, death may occur, due to the displacement of oxygen. The effects associated with various levels of oxygen are described on the PROTECTIVE EQUIPMENT
CONCENTRATION
of OXYGEN EXPOSURE
early symptoms in persons with heart, lung, or circulatory problems. For Routine Industrial Use and Handling Applications Breathing increases, especially in exertion. Pulse up. Impaired coordination, perception, and judgment. Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate
3 = Serious 4 = Severe * = Chronic hazard
Breathing further increases in rate and depth, poor coordination and judgment, lips slightly blue. Mental failure, fainting, unconsciousness, ashen face, blueness of lips, nausea (upset stomach), and vomiting. 8 minutes, may be fatal in 50–100% of cases; 6 minutes, may be fatal in 25 to 50% of cases; 4–5 minutes, recovery with treatment. Coma in 40 seconds, followed by convulsion, breathing failure, death. WARNING: Exposure to atmospheres containing 8–10% or less oxygen will bring about unconsciousness without
warning and so quickly that individuals cannot help or protect themselves. Lack of sufficient oxygen may cause
serious injury or death.
SKIN CONTACT: Transitory skin contact should not cause any adverse effects.
OTHER ACUTE HEALTH EFFECTS: Contact with rapidly expanding gases (which are released from under high
pressure) may cause frostbite. Symptoms of frostbite include change in skin color to white or grayish-yellow. The pain caused
by frostbite can quickly subside, masking the injury. In addition, the sudden release of a pressurized gas (such as may occur
in the event of a valve failure), presents a severe hazard of mechanical injury.
ACUTE EXPOSURE TARGET ORGANS: Respiratory system.
ROUTES OF ENTRY, SYMPTOMS OF CHRONIC EXPOSURE:
INHALATION: In animal tests, rats were exposed by inhalation for 21 days, dosed 6 hours per day, 5 days per week, at
3,300 ppm and no adverse effects of toxicological significance (NOAEL) were observed. At 10,000 ppm, there were signs of
central nervous system depression. However, there were no signs of toxicity or histopathological changes observed and no
potentiation of cardiac sensitization potential. Other animal testing resulted in cardiac sensitization at various concentrations
for varying exposure times. Chronic exposure to oxygen-deficient atmospheres (below 18% oxygen in air) may affect the heart
and nervous system.
H3R Clean Agent Specialists, Inc.
Halon 1211
Page 4 of 11
HALON 1211
SECTION 11. TOXICOLOGICAL INFORMATION (Continued)
ROUTES OF ENTRY, SYMPTOMS OF CHRONIC EXPOSURE (continued):
SKIN CONTACT: Prolonged contact may cause dermatitis (dry, red, cracked skin) due to defatting of the skin.
ACUTE EXPOSURE TARGET ORGANS: Skin, cardiac system, central nervous system.
CARCINOGENIC POTENTIAL: Halon 1211 is not listed as a carcinogen or as a potential carcinogen on EPA, NIOSH,
GERMAN MAK, OSHA, NTP, IARC, or CAL/OSHA Carcinogen lists.
TOXICITY DATA: There toxicology data are currently available for Halon 1211.
BROMOCHLORODIFLUOROMETHANE:
TCLo (Inhalation-Man) 4 pph/1 minute: Peripheral Nerve and Sensation: paresthesis; Behavioral: hallucinations, distorted perceptions; Cardiac: EKG changes
TCLo (Inhalation-Human) 295,200 mg/m3/1 minute: Peripheral Nerve and Sensation: paresthesis LC50 (Inhalation-Rat) 20 pph/15 minutes: Behavioral: tremor, convulsions or effect on seizure threshold; Lungs, Thorax, or Respiration: respiratory depression LC50 (Inhalation-Rat) 2,140,000 mg/m3/5 minutes LCLo (Inhalation-Dog) 5 pph/30 minutes: Behavioral: tremor, convulsions or effect on seizure threshold; Cardiac: other changes LCLo (Inhalation-Guinea Pig) 30 pph/2 hours: Behavioral: convulsions or effect on seizure threshold TCLo (Inhalation-Rat) 396,000 mg/m3/10 minutes: Behavioral: general anesthetic TCLo (Inhalation-Rat) 210 µg/m3/4 hours/12 weeks-intermittent: Blood: pigmented or nucleated red blood cells, changes in erythrocyte (RBC) count, changes in TCLo (Inhalation-Rat) 1 pph/6 hours/3 weeks-intermittent: Behavioral: somnolence (general depressed activity) TCLo (Inhalation-Rat) 50,000 ppm: female 6-15 day(s) after conception: Reproductive: Maternal Effects: other effects Mutation in Microorganisms (Bacteria-Salmonella typhimurium) 10 pph ADDITIONAL TOXICOLOGICAL DATA:
ACUTE: Inhalation-Rat: At 50,000 ppm, no effects were noted. At 75,000 ppm, slightly accelerated respiration was noted. At 100,000 ppm, mild excitement was seen. At 200,000 ppm, within 1 to 2 minutes marked excitation and some convulsions were noted. At 60 to 90 minutes, 2 of the 4 animals died. A concentration of 300,000 ppm immediately gave rise to convulsions and narcosis and all animals died within 50 min. Inhalation-Dog: At 25,000 to 75,000 ppm for 3.5 hours, there was reversible myocardial lesions and fatty degeneration of the liver. CHRONIC: A case of occupational rhabdomyolysis in an individual susceptible to malignant hyperthermia was described. A 43 year old male was found to have a serum creatine-kinase activity of 650 international units per liter, normal range 10 to 200 international units/liter, suggesting that he was susceptible to malignant hyperthermia. His susceptibility was confirmed by in vitro testing of a muscle specimen with halothane and caffeine. The subject was subsequently employed in a factory that made fire extinguishers where one of his jobs consisted of discharging Bromochlorodifluoromethane from fire extinguishers before refilling them. Although discharging was done in open air, some gas was commonly inhaled. Eighteen months after beginning this work, he was examined for complaints of malaise and stiffness and weakness in the forearms and hands. The symptoms progressively worsened during the week and improved the weekends. Serum creatine-kinase activity was 1056 IU/l on one Saturday and 544 IU/l the following Monday. Because of the similarity in structure between Bromochlorodifluoromethane and halothane, the effects of the former on contractions of a muscle specimen were examined. Bromochlorodifluoromethane induced contractions identical to those of halothane. The patient was advised to change jobs. After he did so his symptoms immediately improved. It was concluded that the patient's rhabdomyolysis is due to recurring exposures to Bromochlorodifluoromethane. They recommended that persons susceptible to malignant hyperthermia avoid exposure to similar halogenated hydrocarbons. Inhalation-Human: At 4 to 5% for 1 minute using face mask, subjects at 30 seconds became slightly dizzy and light-headed. Over the next few seconds, these symptoms rapidly increased in severity until at 1 minute the subjects felt as though they were about to lose consciousness and exposure was stopped. Paresthesia of the fingers and other parts of the body was sometimes noted towards the end of the experiment. Heart rate rose by approximately 30% during the early stages of exposure and remained at that level through the experiment. Depression of the T wave was consistently observed on the ECG tracings. The subjects recovered rapidly on cessation of exposure and felt perfectly normal again within 5 minutes. The heart rate and the ECG reverted to normal within 1 minute. There were no delayed after effects. Inhalation-Dog: At 5,000 to 100,000 ppm resulted in cardiac sensitization above 20,000 ppm and in 10 to 0.5 minutes, depending on concentration. IRRITANCY OF PRODUCT: Not applicable.
SENSITIZATION OF PRODUCT: Halon 1211 is not a human skin or respiratory sensitizer, but has been shown to be a
cardiac sensitizer in animal studies.
REPRODUCTIVE TOXICITY INFORMATION: Listed below is information concerning the effects of Halon 1211 on the
human reproductive system.
Mutagenicity: Halon 1211 is not reported to cause mutagenic effects in humans. Embryotoxicity: Halon 1211 is not reported to cause embryotoxic effects in humans. Teratogenicity: Halon 1211 is not reported to cause teratogenic effects in humans. Reproductive Toxicity: Halon 1211 is not reported to cause adverse reproductive effects in humans. A mutagen is a chemical that causes permanent changes to genetic material (DNA) such that the changes will propagate through generational lines. An embryotoxin is a chemical that causes damage to a developing embryo (i.e., within the first eight weeks of pregnancy in humans), but the damage does not propagate across generational lines. A teratogen is a chemical that causes damage to a developing fetus, but the damage does not propagate across generational lines. A reproductive toxin is any substance that interferes in any way with the reproductive process. BIOLOGICAL EXPOSURE INDICES (BEIs): Currently, Biological Exposure Indices (BEIs) have not been determined for
Halon 1211.
H3R Clean Agent Specialists, Inc.
Halon 1211
Page 5 of 11
HALON 1211
SECTION 12. ECOLOGICAL INFORMATION
ALL WORK PRACTICES MUST BE AIMED AT ELIMINATING ENVIRONMENTAL CONTAMINATION.
ENVIRONMENTAL STABILITY: The gas will be dissipated rapidly in well-ventilated areas.
EFFECT OF MATERIAL ON PLANTS or ANIMALS: Immediate adverse effect on plants would be related to oxygen-
deficient environments or frost from rapidly expanding gases, unless exposure occurs in a confined space.
EFFECT OF CHEMICAL ON AQUATIC LIFE: There is currently no evidence of adverse effects from exposure to Halon
1211 on aquatic life.
MOBILITY: Using a structure estimation method based on molecular connectivity indices, the Koc for Halon 1211 can be
estimated to be about 49. According to a classification scheme, this estimated Koc value suggests that Halon 1211 is
expected to have very high mobility in soil.
PERSISTENCE AND BIODEGRADABILITY: Photodegradation: > 50% after 14 years. If released to air, a vapor
pressure of 2.07X10+3 mm Hg at 25°C indicates Halon 1211 will exist solely in the gas phase in the ambient atmosphere. Gas
phase Bromochlorodifluoromethane will slowly be degraded in the atmosphere by reaction with photochemically-produced
hydroxyl radicals; the half-life for this reaction in air is estimated to be greater than 44 years. Halon 1211 absorbs very little UV
radiation above 290 nm and is not expected to photolyze at a significant rate in the ambient atmosphere. Volatilization from
moist soil surfaces is expected to be an important fate process based upon an estimated Henry's Law constant of 9.4X10-2
atm-cu m/mole. Halon 1211 will volatilize rapidly from dry soil surfaces since it exists as a gas in the ambient environment. If
released into water, Halon 1211 is not expected to adsorb to suspended solids and sediment based upon the estimated Koc.
Volatilization from water surfaces is expected to be an important fate process based upon this compound's estimated Henry's
Law constant. Estimated volatilization half-lives for a model river and model lake are 1.3 hrs and 5.1 days, respectively. Given
its high degree of halogenation, it is not expected to be an important degradation pathway for Halon 1211.
POTENTIAL TO BIOACCUMULATE: An estimated BCF of 5.8 was calculated for Halon 1211, using an estimated log
Kow of 1.9 and a regression-derived equation. According to a classification scheme, this BCF suggests the potential for
bioconcentration in aquatic organisms is low.
OZONE-DEPLETION POTENTIAL: Halon 1211 is rated as 3 (compared to trichlorofluoromethane nominally 1). Halon
1211 is a Class I ozone depleting chemical (40 CFR Part 82). Halon 1211 may contribute to global warming.
SECTION 13. DISPOSAL CONSIDERATIONS
UNUSED PRODUCT / EMPTY CONTAINER: Do not dispose of residual product. Return used product in cylinders to: H3R
Clean Agent Specialists, Inc.
DISPOSAL INFORMATION: Relative to the environment, this material has an ozone depletion potential and a global
warming potential. Refer to the regulations of the U.S. EPA or the State-specific regulations for proper waste disposal, regulations
of Canada and its Provinces, or regulations of EU member states.
SECTION 14. TRANSPORT INFORMATION
The following shipping information applies when this product is supplied in fire-extinguishing cylinders:
U.S. SHIPPING INFORMATION:
U.S. DOT PROPER SHIPPING NAME:
Fire extinguisher with compressed or liquefied gas UN IDENTIFICATION NUMBER: UN
HAZARD CLASS NUMBER and DESCRIPTION:
U.S. DOT SHIPPING LABEL(S) REQUIRED:
PACKING GROUP: Not
PLACARD (When required):
SPECIAL SHIPPING INFORMATION: Cylinders should be transported in a secure position in a well-ventilated truck (never
transport in passenger compartment of a vehicle). Ensure cylinder valve is properly closed, valve outlet cap has been reinstalled, and valve protection cap is secured before shipping cylinder. CAUTION: Compressed gas cylinders shall not be refilled except by qualified producers of compressed gases. Shipment of a
compressed gas cylinder which has not been filled by the owner or with the owner’s written consent is a violation of Federal law (49 CFR 173.301). ERG (EMERGENCY RESPONSE GUIDEBOOK) #: 126
SPECIAL PROVISIONS: T50 Portable tanks - Applies to various liquefied compressed gases: Consult the regulations for
specific requirements Sec. 172.102 Special Provision Portable Tank Code T50. CANADIAN SHIPPING INFORMATION:
TRANSPORT CANADA TRANSPORTATION OF DANGEROUS GOODS REGULATIONS: This product is classified as
Dangerous Goods, per regulations of Transport Canada. The use of the above U.S. DOT information from the U.S. 49 CFR regulations is allowed for shipments that originate in the U.S. For shipments via ground vehicle or rail that originate in Canada, the following information is applicable. PROPER SHIPPING NAME:
Fire extinguisher with compressed or liquefied gas UN IDENTIFICATION NUMBER: UN
HAZARD CLASS NUMBER and DESCRIPTION:
PACKING GROUP: Not
HAZARD SHIPPING LABEL(S) REQUIRED:
H3R Clean Agent Specialists, Inc.
Halon 1211
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HALON 1211
SECTION 14. TRANSPORT INFORMATION (Continued)
CANADIAN SHIPPING INFORMATION (continued):
TRANSPORT CANADA TRANSPORTATION OF DANGEROUS GOODS REGULATIONS (continued):
SPECIAL PROVISIONS:
EXPLOSIVE LIMIT & LIMITED QUANTITY INDEX:
ERAP INDEX:
PASSENGER CARRYING SHIP INDEX:
PASSENGER CARRYING ROAD OR RAIL VEHICLE INDEX: 75
INTERNATIONAL AIR TRANSPORT ASSOCIATION SHIPPING INFORMATION (IATA):
UN IDENTIFICATION NUMBER:
PROPER SHIPPING NAME/DESCRIPTION:
Fire extinguisher with compressed or liquefied gas HAZARD CLASS or DIVISION:
HAZARD LABEL(S) REQUIRED:
PACKING GROUP:
PASSENGER and CARGO AIRCRAFT PACKING INSTRUCTION: 213
PASSENGER and CARGO AIRCRAFT MAXIMUM NET QUANTITY PER PKG: 75 kg
PASSENGER and CARGO AIRCRAFT LIMITED QUANTITY PACKING INSTRUCTION:
PASSENGER and CARGO AIRCRAFT LIMITED QUANTITY MAXIMUM NET QUANTITY PER PKG: None
CARGO AIRCRAFT ONLY PACKING INSTRUCTION: 213
CARGO AIRCRAFT ONLY MAXIMUM NET QUANTITY PER PKG: 150 kg
SPECIAL PROVISIONS:
ERG CODE: 2L
INTERNATIONAL MARITIME ORGANIZATION SHIPPING INFORMATION (IMO):
UN No.: 1044
PROPER SHIPPING NAME:
Fire extinguisher with compressed or liquefied gas HAZARD CLASS NUMBER: 2.2
PACKING GROUP:
SPECIAL PROVISIONS: 225
LIMITED QUANTITIES: 120
PACKING INSTRUCTIONS: P003
EmS: F-C,
STOWAGE CATEGORY:
MARINE POLLUTANT: This material is not designated by the IMO to be a Marine Pollutant.
EUROPEAN SHIPPING INFORMATION:
EUROPEAN AGREEMENT CONCERNING THE INTERNATIONAL CARRIAGE OF DANGEROUS GOODS BY ROAD
(ADR): This material is classified by the Economic Commission for Europe to be dangerous goods. Additional
information is as follows:
UN NO.: 1044
NAME and DESCRIPTON:
Fire extinguisher with compressed or liquefied gas CLASSIFICATION CODE: 6A
PACKING GROUP: None
LABELS: 2.2
SPECIAL PROVISIONS: 225,
LIMITED QUANTITIES: LQ0
PACKING INSTRUCTIONS: P003
MIXED PACKING PROVISIONS: MP9
HAZARD IDENTIFICATION No.: None
The following shipping information applies when the product is supplied in types of cylinders other than fire
extinguishers:
U.S. SHIPPING INFORMATION:
U.S. DOT PROPER SHIPPING NAME: Chlorodifluorobromomethane
or Refrigerant gas R12B1
UN IDENTIFICATION NUMBER: UN
HAZARD CLASS NUMBER and DESCRIPTION:
U.S. DOT SHIPPING LABEL(S) REQUIRED:
PACKING GROUP: Not
PLACARD (When required):
SPECIAL SHIPPING INFORMATION: Cylinders should be transported in a secure position in a well-ventilated truck (never
transport in passenger compartment of a vehicle). Ensure cylinder valve is properly closed, valve outlet cap has been reinstalled, and valve protection cap is secured before shipping cylinder. CAUTION: Compressed gas cylinders shall not be refilled except by qualified producers of compressed gases. Shipment of a
compressed gas cylinder which has not been filled by the owner or with the owner’s written consent is a violation of Federal law (49 CFR 173.301). H3R Clean Agent Specialists, Inc.
Halon 1211
Page 7 of 11
HALON 1211
SECTION 14. TRANSPORT INFORMATION (Continued)
U.S. SHIPPING INFORMATION (continued):
ERG (EMERGENCY RESPONSE GUIDEBOOK) #: 126
SPECIAL PROVISIONS: T50 Portable tanks - Applies to various liquefied compressed gases: Consult the regulations for
specific requirements Sec. 172.102 Special Provision Portable Tank Code T50. CANADIAN SHIPPING INFORMATION:
TRANSPORT CANADA TRANSPORTATION OF DANGEROUS GOODS REGULATIONS: This gas is classified as
Dangerous Goods, per regulations of Transport Canada. The use of the above U.S. DOT information from the U.S. 49 CFR regulations is allowed for shipments that originate in the U.S. For shipments via ground vehicle or rail that originate in Canada, the following information is applicable. PROPER SHIPPING NAME: Chlorodifluorobromomethane
or Refrigerant gas R12B1
UN IDENTIFICATION NUMBER: UN
HAZARD CLASS NUMBER and DESCRIPTION:
PACKING GROUP: Not
HAZARD SHIPPING LABEL(S) REQUIRED:
SPECIAL PROVISIONS:
EXPLOSIVE LIMIT & LIMITED QUANTITY INDEX:
ERAP INDEX:
PASSENGER CARRYING SHIP INDEX:
PASSENGER CARRYING ROAD OR RAIL VEHICLE INDEX: 75
INTERNATIONAL AIR TRANSPORT ASSOCIATION SHIPPING INFORMATION (IATA):
UN IDENTIFICATION NUMBER:
PROPER SHIPPING NAME/DESCRIPTION: Chlorodifluorobromomethane
HAZARD CLASS or DIVISION:
HAZARD LABEL(S) REQUIRED:
PACKING GROUP:
PASSENGER and CARGO AIRCRAFT PACKING INSTRUCTION: 200
PASSENGER and CARGO AIRCRAFT MAXIMUM NET QUANTITY PER PKG: 75 kg
PASSENGER and CARGO AIRCRAFT LIMITED QUANTITY PACKING INSTRUCTION:
PASSENGER and CARGO AIRCRAFT LIMITED QUANTITY MAXIMUM NET QUANTITY PER PKG: None
CARGO AIRCRAFT ONLY PACKING INSTRUCTION: 200
CARGO AIRCRAFT ONLY MAXIMUM NET QUANTITY PER PKG: 150 kg
SPECIAL PROVISIONS:
ERG CODE: 2L
INTERNATIONAL MARITIME ORGANIZATION SHIPPING INFORMATION (IMO):
UN No.: 1974
PROPER SHIPPING NAME: Chlorodifluorobromomethane
or Refrigerant gas R12B1
HAZARD CLASS NUMBER: 2.2
PACKING GROUP:
SPECIAL PROVISIONS: None
LIMITED QUANTITIES: 120
PACKING INSTRUCTIONS: P200
EmS: F-C,
STOWAGE CATEGORY: Category
MARINE POLLUTANT: This material is not designated by the IMO to be a Marine Pollutant.
EUROPEAN SHIPPING INFORMATION:
EUROPEAN AGREEMENT CONCERNING THE INTERNATIONAL CARRIAGE OF DANGEROUS GOODS BY ROAD
(ADR): This material is classified by the Economic Commission for Europe to be dangerous goods. Additional
information is as follows:
UN NO.: 1974
NAME and DESCRIPTON:
Chlorodifluorobromomethane or Refrigerant gas R12B1
CLASSIFICATION CODE: 2A
PACKING GROUP: None
LABELS: 2.2
SPECIAL PROVISIONS: None
LIMITED QUANTITIES: LQ1
PACKING INSTRUCTIONS: P200
MIXED PACKING PROVISIONS: MP9
HAZARD IDENTIFICATION No.: 20
H3R Clean Agent Specialists, Inc.
Halon 1211
Page 8 of 11
HALON 1211
SECTION 15. REGULATORY INFORMATION
U.S. FEDERAL REGULATIONS:
EPA - ENVIRONMENTAL PROTECTION AGENCY:
CERCLA: Comprehensive Environmental Response, Compensation, and Liability Act of 1990 (40 CFR Parts 117 and 302)
Reportable Quantity (RQ): Not Applicable SARA TITLE III: Superfund Amendment and Reauthorization Act
SECTIONS 302/304: Emergency Planning and Notification (40 CFR Part 355)
Extremely Hazardous Substances: Halon 1211 is not listed. Threshold Planning Quantity (TPQ): Not Applicable Reportable Quantity (RQ): Not Applicable SECTIONS 311/312: Hazardous Chemical Reporting (40 CFR Part 370)
SECTION 313: Toxic Chemical Release Reporting (40 CFR 372)
Releases of Halon 1211 require reporting under Section 313. CLEAN AIR ACT:
SECTION 112 (r): Risk Management Programs for Chemical Accidental Release (40 CFR Part 68)
Threshold Planning Quantity (TPQ): Not Applicable TSCA: Toxic Substances Control Act
Halon 1211 is listed in the TSCA Inventory OSHA - OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION:
29 CFR Part 1910.119: Process Safety Management of Highly Hazardous Chemicals.
Threshold Planning Quantity (TPQ): Not Applicable OTHER U.S. FEDERAL REGULATIONS: Requirements under (40 CFR Part 82) may be applicable as Halon 1211 is
designated as an ozone-depleting compound.
U.S. STATE REGULATORY INFORMATION:
CALIFORNIA PROPOSITION 65: Halon 1211 is NOT listed on the California Proposition 65 lists.
CANADIAN FEDERAL REGULATIONS:
CANADIAN DSL INVENTORY STATUS: Halon 1211 is listed on the DSL Inventory.
OTHER CANADIAN REGULATIONS: Halon 1211 is categorized as a Controlled Product, Hazard Class A, as per the
Controlled Product Regulations. Halon 1211 is not on the CEPA Priorities Substances Lists.
CANADIAN WHMIS CLASSIFICATION and SYMBOLS:
Class A: Compressed Gas

EUROPEAN UNION REGULATIONS:
EU LABELING AND CLASSIFICATION: Currently, this substance is not classified, as per European Union Council
Directives 67/548/EEC and 1999/45/EC and subsequent Directives.
EU CLASSIFICATION: Not Applicable
EU RISK PHRASES: Not Applicable
EUROPEAN UNION ANNEX II HAZARD SYMBOL: Not Applicable
SECTION 16. OTHER INFORMATION
Information contained in this Material Safety Data Sheet is provided to our customers so they may comply with 29 CFR 1910.1200, Hazard Communication Standard, the Canadian WHMIS Standard, and the requirements of the European Union Directives. The intent of this Material Safety Data Sheet is to provide end users of this product with the health and physical hazards associated with possible exposure to this product. All statements, technical data and recommendations are based on readily available texts and data that H3R Clean Agent Specialists, Inc., believes to be reliable and accurate. Clean Agent Specialists, Inc. makes no warranties, guarantees or representations of any kind with respect to this product or this data. It is the responsibility of the user to obtain and use the most recent version of this MSDS. PREPARED BY:
August 2009: Review and up-date of MSDS to current Standards. DEFINITIONS OF TERMS
A large number of abbreviations and acronyms appear on a MSDS. Some of these which are commonly used include the following: CAS #: This is the Chemical Abstract Service Number that uniquely identifies each
EXPOSURE LIMITS IN AIR (continued):
DFG MAK Germ Cell Mutagen Categories (continued): 3B: Substances which are
EXPOSURE LIMITS IN AIR:
suspected of being germ cell mutagens because of their genotoxic effects in mammalian CEILING LEVEL: The concentration that shall not be exceeded during any part of the
somatic cell in vivo; in exceptional cases, substances for which there are no in vivo data, but which are clearly mutagenic in vitro and structurally related to known in vivo DFG MAK Germ Cell Mutagen Categories: 1: Germ cell mutagens which have been
mutagens. 4: Not applicable (Category 4 carcinogenic substances are those with non-
shown to increase the mutant frequency in the progeny of exposed humans. 2: Germ
genotoxic mechanisms of action. By definition, germ cell mutagens are genotoxic. cell mutagens which have been shown to increase the mutant frequency in the progeny Therefore, a Category 4 for germ cell mutagens cannot apply. At some time in the of exposed mammals. 3A: Substances which have been shown to induce genetic
future, it is conceivable that a Category 4 could be established for genotoxic substances damage in germ cells of human of animals, or which produce mutagenic effects in with primary targets other than DNA [e.g. purely aneugenic substances] if research somatic cells of mammals in vivo and have been shown to reach the germ cells in an results make this seem sensible.) 5: Germ cell mutagens, the potency of which is
considered to be so low that, provided the MAK value is observed, their contribution to genetic risk for humans is expected not to be significant. H3R Clean Agent Specialists, Inc.
Halon 1211
Page 9 of 11
HALON 1211
DEFINITIONS OF TERMS (Continued)
EXPOSURE LIMITS IN AIR (continued):
HAZARDOUS MATERIALS IDENTIFICATION SYSTEM
DFG MAK Pregnancy Risk Group Classification: Group A: A risk of damage to the
HAZARD RATINGS (continued):
developing embryo or fetus has been unequivocally demonstrated. Exposure of FLAMMABILITY HAZARD (continued): 3 (Serious Hazard- Liquids and solids that can
pregnant women can lead to damage of the developing organism, even when MAK and be ignited under almost all ambient temperature conditions. Materials in this degree BAT (Biological Tolerance Value for Working Materials) values are observed. Group B:
produce hazardous atmospheres with air under almost all ambient temperatures, or, Currently available information indicates a risk of damage to the developing embryo or unaffected by ambient temperature, are readily ignited under almost all conditions, fetus must be considered to be probable. Damage to the developing organism cannot including: Liquids having a flash point below 22.8°C [73°F] and having a boiling point at be excluded when pregnant women are exposed, even when MAK and BAT values are
observed. Group C: There is no reason to fear a risk of damage to the developing
or above 38°C [100°F] and below 37.8°C [100°F] [e.g. OSHA Class IB and IC]; Materials embryo or fetus when MAK and BAT values are observed. Group D: Classification in
that on account of their physical form or environmental conditions can form explosive one of the groups A-C is not yet possible because, although the data available may mixtures with air and are readily dispersed in air [e.g., dusts of combustible solids, mists indicate a trend, they are not sufficient for final evaluation. or droplets of flammable liquids]; Materials that burn extremely rapidly, usually by reason IDLH-Immediately Dangerous to Life and Health: This level represents a
of self-contained oxygen [e.g. dry nitrocellulose and many organic peroxides]);4 (Severe
concentration from which one can escape within 30-minutes without suffering escape- Hazard-Materials that will rapidly or completely vaporize at atmospheric pressure and normal ambient temperature or that are readily dispersed in air, and which will burn LOQ: Limit of Quantitation.
readily, including: Flammable gases; Flammable cryogenic materials; Any liquid or MAK: Federal Republic of Germany Maximum Concentration Values in the workplace.
gaseous material that is liquid while under pressure and has a flash point below 22.8°C NE: Not Established. When no exposure guidelines are established, an entry of NE is
[73°F] and a boiling point below 37.8°C [100°F] [e.g. OSHA Class IA; Material that ignite spontaneously when exposed to air at a temperature of 54.4°C [130°F] or below [e.g. NIC: Notice of Intended Change.
NIOSH CEILING: The exposure that shall not be exceeded during any part of the
PHYSICAL HAZARD: 0 (Water Reactivity: Materials that do not react with water.
workday. If instantaneous monitoring is not feasible, the ceiling shall be assumed as a Organic Peroxides: Materials that are normally stable, even under fire conditions and will 15-minute TWA exposure (unless otherwise specified) that shall not be exceeded at any not react with water. Explosives: Substances that are Non-Explosive. Unstable Compressed Gases: No Rating. Pyrophorics: No Rating. Oxidizers: No “0” rating NIOSH RELs: NIOSH’s Recommended Exposure Limits.
allowed. Unstable Reactives: Substances that will not polymerize, decompose, PEL-Permissible Exposure Limit: OSHA’s Permissible Exposure Limits. This
condense or self-react.); 1 (Water Reactivity: Materials that change or decompose upon
exposure value means exactly the same as a TLV, except that it is enforceable by exposure to moisture. Organic Peroxides: Materials that are normally stable, but can OSHA. The OSHA Permissible Exposure Limits are based in the 1989 PELs and the become unstable at high temperatures and pressures. These materials may react with June, 1993 Air Contaminants Rule (Federal Register: 58: 35338-35351 and 58: 40191). water, but will not release energy. Explosives: Division 1.5 & 1.6 substances that are Both the current PELs and the vacated PELs are indicated. The phrase, “Vacated 1989 very insensitive explosives or that do not have a mass explosion hazard. Compressed PEL,” is placed next to the PEL that was vacated by Court Order. Gases: Pressure below OSHA definition. Pyrophorics: No Rating. Oxidizers: SKIN: Used when a there is a danger of cutaneous absorption.
Packaging Group III; Solids: any material that in either concentration tested, exhibits a STEL-Short Term Exposure Limit: Short Term Exposure Limit, usually a 15-minute
mean burning time less than or equal to the mean burning time of a 3:7 potassium time-weighted average (TWA) exposure that should not be exceeded at any time during bromate/cellulose mixture and the criteria for Packing Group I and II are not met. a workday, even if the 8-hr TWA is within the TLV-TWA, PEL-TWA or REL-TWA. Liquids: any material that exhibits a mean pressure rise time less than or equal to the SKIN: Used when a there is a danger of cutaneous absorption.
pressure rise time of a 1:1 nitric acid (65%)/cellulose mixture and the criteria for Packing STEL-Short Term Exposure Limit: Short Term Exposure Limit, usually a 15-minute
Group I and II are not met. Unstable Reactives: Substances that may decompose, time-weighted average (TWA) exposure that should not be exceeded at any time during condense or self-react, but only under conditions of high temperature and/or pressure a workday, even if the 8-hr TWA is within the TLV-TWA, PEL-TWA or REL-TWA. and have little or no potential to cause significant heat generation or explosive hazard. Substances that readily undergo hazardous polymerization in the absence of inhibitors.); TLV-Threshold Limit Value: An airborne concentration of a substance that represents
conditions under which it is generally believed that nearly all workers may be repeatedly
2 (Water Reactivity: Materials that may react violently with water. Organic Peroxides:
exposed without adverse effect. The duration must be considered, including the 8-hour. Materials that, in themselves, are normally unstable and will readily undergo violent chemical change, but will not detonate. These materials may also react violently with TWA-Time Weighted Average: Time Weighted Average exposure concentration for a
water. Explosives: Division 1.4 – Explosive substances where the explosive effect are conventional 8-hr (TLV, PEL) or up to a 10-hr (REL) workday and a 40-hr workweek. largely confined to the package and no projection of fragments of appreciable size or HAZARDOUS MATERIALS IDENTIFICATION SYSTEM range are expected. An external fire must not cause virtually instantaneous explosion of
HAZARD RATINGS: This rating system was developed by the National Paint
almost the entire contents of the package. Compressed Gases: Pressurized and meet and Coating Association and has been adopted by industry to identify the degree of OSHA definition but < 514.7 psi absolute at 21.1°C (70°F) [500 psig]. Pyrophorics: No Rating. Oxidizers: Packing Group II Solids: any material that, either in concentration HEALTH HAZARD: 0 (Minimal Hazard: No significant health risk, irritation of skin or
tested, exhibits a mean burning time of less than or equal to the mean burning time of a eyes not anticipated. Skin Irritation: Essentially non-irritating. PII or Draize = “0”. Eye 2:3 potassium bromate/cellulose mixture and the criteria for Packing Group I are not met. Irritation: Essentially non-irritating, or minimal effects which clear in < 24 hours [e.g. Liquids: any material that exhibits a mean pressure rise time less than or equal to the mechanical irritation]. Draize = “0”. Oral Toxicity LD pressure rise of a 1:1 aqueous sodium chlorate solution (40%)/cellulose mixture and the 50 Rat: < 5000 mg/kg. Dermal criteria for Packing Group I are not met. Unstable Reactives: Substances that may 50Rat or Rabbit: < 2000 mg/kg. Inhalation Toxicity 4-hrs LC50 Rat: < 20 mg/L.); 1 (Slight Hazard: Minor reversible Injury may occur; slightly or mildly irritating.
polymerize, decompose, condense, or self-react at ambient temperature and/or Skin Irritation: Slightly or mildly irritating. Eye Irritation: Slightly or mildly irritating. Oral pressure, but have a low potential for significant heat generation or explosion. Substances that readily form peroxides upon exposure to air or oxygen at room 50 Rat: > 500-5000 mg/kg. Dermal Toxicity LD50Rat or Rabbit: > 1000-2000 temperature); 3 (Water Reactivity: Materials that may form explosive reactions with
50 4-hrs Rat: > 2-20 mg/L); 2 (Moderate Hazard: Temporary
or transitory injury may occur. Skin Irritation: Moderately irritating; primary irritant; water. Organic Peroxides: Materials that are capable of detonation or explosive reaction, sensitizer. PII or Draize > 0, < 5. Eye Irritation: Moderately to severely irritating and/or but require a strong initiating source, or must be heated under confinement before corrosive; reversible corneal opacity; corneal involvement or irritation clearing in 8-21 initiation; or materials that react explosively with water. Explosives: Division 1.2 – days. Draize > 0, < 25. Oral Toxicity LD Explosive substances that have a fire hazard and either a minor blast hazard or a minor 50 Rat: > 50-500 mg/kg. Dermal Toxicity LD50Rat or Rabbit: > 200-1000 mg/kg. Inhalation Toxicity LC projection hazard or both, but do not have a mass explosion hazard. Compressed 50 4-hrs Rat: > 0.5-2 mg/L.); 3
(Serious Hazard: Major injury likely unless prompt action is taken and medical treatment Gases: Pressure > 514.7 psi absolute at 21.1°C (70°F) [500 psig]. Pyrophorics: No is given; high level of toxicity; corrosive. Skin Irritation: Severely irritating and/or Rating. Oxidizers: Packing Group I Solids: any material that, in either concentration corrosive; may destroy dermal tissue, cause skin burns, dermal necrosis. PII or Draize > tested, exhibits a mean burning time less than the mean burning time of a 3.:2 potassium 5-8 with destruction of tissue. Eye Irritation: Corrosive, irreversible destruction of ocular bromate/cellulose mixture. Liquids: Any material that spontaneously ignites when mixed tissue; corneal involvement or irritation persisting for more than 21 days. Draize > 80 with cellulose in a 1:1 ratio, or which exhibits a mean pressure rise time less than the with effects irreversible in 21 days. Oral Toxicity LD pressure rise time of a 1:1 perchloric acid (50%)/cellulose mixture. Unstable Reactives 50 Rat: > 1-50 mg/kg. Dermal :Substances that may polymerize, decompose, condense or self-react at ambient 50Rat or Rabbit: > 20-200 mg/kg. Inhalation Toxicity LC50 4-hrs Rat: > 0.05- 0.5 mg/L.); 4 (Severe Hazard: Life-threatening; major or permanent damage may result
temperature and/or pressure and have a moderate potential to cause significant heat from single or repeated exposure. Skin Irritation: Not appropriate. Do not rate as a “4”, generation or explosion.); 4 Water Reactivity: Materials that react explosively with water
based on skin irritation alone. Eye Irritation: Not appropriate. Do not rate as a “4”, without requiring heat or confinement. Organic Peroxides: Materials that are readily based on eye irritation alone. Oral Toxicity LD capable of detonation or explosive decomposition at normal temperature and pressures. 50 Rat: < 1 mg/kg. Dermal Toxicity Explosives: Division 1.1 & 1.2-explosive substances that have a mass explosion hazard 50Rat or Rabbit: < 20 mg/kg. Inhalation Toxicity LC50 4-hrs Rat: < 0.05 mg/L). FLAMMABILITY HAZARD: 0 (Minimal Hazard-Materials that will not burn in air when
or have a projection hazard. A mass explosion is one that affects almost the entire load exposure to a temperature of 815.5°C [1500°F] for a period of 5 minutes.); 1 (Slight
instantaneously. Compressed Gases: No Rating. Pyrophorics: Add to the definition of Hazard-Materials that must be pre-heated before ignition can occur. Material require Flammability “4”. Oxidizers: No “4” rating. Unstable Reactives: Substances that may considerable pre-heating, under all ambient temperature conditions before ignition and polymerize, decompose, condense or self-react at ambient temperature and/or pressure combustion can occur, Including: Materials that will burn in air when exposed to a and have a high potential to cause significant heat generation or explosion. temperature of 815.5°C (1500°F) for a period of 5 minutes or less; Liquids, solids and NATIONAL FIRE PROTECTION ASSOCIATION HAZARD
semisolids having a flash point at or above 93.3°C [200°F] (e.g. OSHA Class IIIB, or; RATINGS:
Most ordinary combustible materials [e.g. wood, paper, etc.]; 2 (Moderate Hazard-
HEALTH HAZARD: 0 (materials that, under emergency conditions, would offer no
Materials that must be moderately heated or exposed to relatively high ambient hazard beyond that of ordinary combustible materials): Gases and vapors whose LC temperatures before ignition can occur. Materials in this degree would not, under normal for acute inhalation toxicity is greater than 10,000 ppm. Dusts and mists whose LC conditions, form hazardous atmospheres in air, but under high ambient temperatures or for acute inhalation toxicity is greater than 200 mg/L. Materials whose LD moderate heating may release vapor in sufficient quantities to produce hazardous dermal toxicity is greater than 2000 mg/kg. Materials whose LD50 for acute oral atmospheres in air, Including: Liquids having a flash-point at or above 37.8°C [100°F]; toxicity is greater than 2000 mg/kg. Materials that are essentially non-irritating to the Solid materials in the form of course dusts that may burn rapidly but that generally do not form explosive atmospheres; Solid materials in a fibrous or shredded form that may burn rapidly and create flash fire hazards (e.g. cotton, sisal, hemp; Solids and semisolids that readily give off flammable vapors.); H3R Clean Agent Specialists, Inc.
Halon 1211
Page 10 of 11
HALON 1211
DEFINITIONS OF TERMS (Continued)
NATIONAL FIRE PROTECTION ASSOCIATION HAZARD
NATIONAL FIRE PROTECTION ASSOCIATION HAZARD
RATINGS (continued):
RATINGS (continued):
HEALTH HAZARD (continued): 1 (materials that, under emergency conditions, can
FLAMMABILITY HAZARD (continued): 3 (continued): Flammable or combustible
cause significant irritation): Gases and vapors whose LC50 for acute inhalation toxicity dusts with a representative diameter less than 420 microns (40 mesh). Materials that is greater than 5,000 ppm but less than or equal to 10,000 ppm. Dusts and mists burn with extreme rapidity, usually by reason of self-contained oxygen (e.g. dry whose LC50 for acute inhalation toxicity is greater than 10 mg/L but less than or equal nitrocellulose and many organic peroxides). Solids containing greater than 0.5 to 200 mg/L. Materials whose LD50 for acute dermal toxicity is greater than 1000 percent by weight of a flammable or combustible solvent are rated by the closed cup mg/kg but less than or equal to 2000 mg/kg. Materials whose LD50 for acute oral flash point of the solvent. 4 Materials that will rapidly or completely vaporize at
toxicity is greater than 500 mg/kg but less than or equal to 2000 mg/kg. Materials atmospheric pressure and normal ambient temperature or that are readily dispersed that cause slight to moderate irritation to the respiratory tract, eyes and skin. 2
in air and will burn readily: Flammable gases. Flammable cryogenic materials. Any (materials that, under emergency conditions, can cause temporary incapacitation or liquid or gaseous materials that is liquid while under pressure and has a flash point residual injury): Gases and vapors whose LC50 for acute inhalation toxicity is greater below 22.8°C (73°F) and a boiling point below 37.8°C (100°F) (i.e. Class IA liquids). than 3,000 ppm but less than or equal to 5,000 ppm. Dusts and mists whose LC50 Materials that ignite when exposed to air, Solids containing greater than 0.5 percent for acute inhalation toxicity is greater than 2 mg/L but less than or equal to 10 mg/L. by weight of a flammable or combustible solvent are rated by the closed cup flash Materials whose LD50 for acute dermal toxicity is greater than 200 mg/kg but less than or equal to 1000 mg/kg. Materials whose LD50 for acute oral toxicity is greater INSTABILITY HAZARD: 0 Materials that in themselves are normally stable, even
than 50 mg/kg but less than or equal to 500 mg/kg. Any liquid whose saturated under fire conditions: Materials that have an estimated instantaneous power density vapor concentration at 20°C (68°F) is equal to or greater than one-fifth its LC50 for (product of heat of reaction and reaction rate) at 250°C (482°F) below 0.01 W/mL. acute inhalation toxicity, if its LC50 is less than or equal to 5000 ppm and that does Materials that do not exhibit an exotherm at temperatures less than or equal to 500°C not meet the criteria for either degree of hazard 3 or degree of hazard 4. (932°F) when tested by differential scanning calorimetry. 1 Materials that in themselves
Compressed liquefied gases with boiling points between -30°C (-22°F) and -55°C (- are normally stable, but that can become unstable at elevated temperatures and 66.5°F) that cause severe tissue damage, depending on duration of exposure. pressures: Materials that have an estimated instantaneous power density (product of Materials that are respiratory irritants. Materials that cause severe, but reversible heat of reaction and reaction rate) at 250°C (482°F) at or above 0.01 W/mL and below irritation to the eyes or are lachrymators. Materials that are primary skin irritants or 10 W/mL. 2 Materials that readily undergo violent chemical change at elevated
sensitizers. 3 (materials that, under emergency conditions, can cause serious or
temperatures and pressures: Materials that have an estimated instantaneous power permanent injury): Gases and vapors whose LC50 for acute inhalation toxicity is density (product of heat of reaction and reaction rate) at 250°C (482°F) at or above 10 greater than 1,000 ppm but less than or equal to 3,000 ppm. Dusts and mists whose W/mL and below 100W/mL. 3 Materials that in themselves are capable of detonation
LC50 for acute inhalation toxicity is greater than 0.5 mg/L but less than or equal to 2 or explosive decomposition or explosive reaction, but that require a strong initiating mg/L. Materials whose LD50 for acute dermal toxicity is greater than 40 mg/kg but source or that must be heated under confinement before initiation: Materials that less than or equal to 200 mg/kg. Materials whose LD50 for acute oral toxicity is have an estimated instantaneous power density (product of heat of reaction and reaction greater than 5 mg/kg but less than or equal to 50 mg/kg. Any liquid whose saturated rate) at 250°C (482°F) at or above 100 W/mL and below 1000 W/mL. Materials that are vapor concentration at 20°C (68°F) is equal to or greater than one-fifth its LC50 for sensitive to thermal or mechanical shock at elevated temperatures and pressures. 4
acute inhalation toxicity, if its LC50 is less than or equal to 3000 ppm and that does Materials that in themselves are readily capable of detonation or explosive not meet the criteria for degree of hazard 4. Compressed liquefied gases with boiling decomposition or explosive reaction at normal temperatures and pressures: points between -30°C (-22°F) and -55°C (-66.5°F) that cause frostbite and Materials that have an estimated instantaneous power density (product of heat of irreversible tissue damage. Materials that are respiratory irritants. Cryogenic gases reaction and reaction rate) at 250°C (482°F) of 1000 W/mL or greater. Materials that are that cause frostbite and irreversible tissue damage. Materials that are corrosive to sensitive to localized thermal or mechanical shock at normal temperatures and the respiratory tract. Materials that are corrosive to the eyes or cause irreversible corneal opacity. Materials that are corrosive to the skin. 4 (materials that, under
FLAMMABILITY LIMITS IN AIR:
emergency conditions, can be lethal): Gases and vapors whose LC50 for acute inhalation toxicity less than or equal to 1,000 ppm. Dusts and mists whose LC Much of the information related to fire and explosion is derived from the National Fire
acute inhalation toxicity is less than or equal to 0.5 mg/L. Materials whose LD Protection Association (NFPA). Flash Point - Minimum temperature at which a liquid
acute dermal toxicity is less than or equal to 40 mg/kg. Materials whose LD gives off sufficient vapors to form an ignitable mixture with air. Autoignition Temperature: acute oral toxicity is less than or equal to 5 mg/kg. Any liquid whose saturated vapor The minimum temperature required to initiate combustion in air with no other source of concentration at 20°C (68°F) is equal to or greater than one-fifth its LC ignition. LEL - the lowest percent of vapor in air, by volume, that will explode or ignite in the presence of an ignition source. UEL - the highest percent of vapor in air, by volume, FLAMMABILITY HAZARD: 0 Materials that will not burn under typical fire
that will explode or ignite in the presence of an ignition source. conditions, including intrinsically noncombustible materials such as concrete, stone, TOXICOLOGICAL INFORMATION:
and sand: Materials that will not burn in air when exposed to a temperature of 816°C Human and Animal Toxicology: Possible health hazards as derived from human data,
(1500°F) for a period of 5 minutes in according with Annex D. 1 Materials that must be
animal studies, or from the results of studies with similar compounds are presented. preheated before ignition can occur. Materials in this degree require considerable Definitions of some terms used in this section are: LD50 - Lethal Dose (solids & liquids)
preheating, under all ambient temperature conditions, before ignition and combustion which kills 50% of the exposed animals; LC50 - Lethal Concentration (gases) which kills
can occur: Materials that will burn in air when exposed to a temperature of 816°C 50% of the exposed animals; ppm concentration expressed in parts of material per
(1500°F) for a period of 5 minutes in accordance with Annex D. Liquids, solids and million parts of air or water; mg/m3 concentration expressed in weight of substance per
semisolids having a flash point at or above 93.4°C (200°F) (i.e. Class IIIB liquids). volume of air; mg/kg quantity of material, by weight, administered to a test subject,
Liquids with a flash point greater than 35°C (95°F) that do not sustain combustion when based on their body weight in kg. Other measures of toxicity include TDLo, the lowest
tested using the Method of Testing for Sustained Combustibility, per 49 CFR 173, dose to cause a symptom and TCLo the lowest concentration to cause a symptom;
Appendix H or the UN Recommendation on the Transport of Dangerous Goods, Model TDo, LDLo, and LDo, or TC, TCo, LCLo, and LCo, the lowest dose (or concentration)
Regulations (current edition) and the related Manual of Tests and Criteria (current to cause lethal or toxic effects. Cancer Information: The sources are: IARC - the
edition). Liquids with a flash point greater than 35°C (95°F) in a water-miscible solution International Agency for Research on Cancer; NTP - the National Toxicology Program,
or dispersion with a water non-combustible liquid/solid content of more than 85 percent RTECS - the Registry of Toxic Effects of Chemical Substances, OSHA and CAL/OSHA.
by weight. Liquids that have no fire point when tested by ASTM D 92 Standard Test IARC and NTP rate chemicals on a scale of decreasing potential to cause human cancer Method for Flash and Fire Points by Cleveland Open Cup, up to a boiling point of the with rankings from 1 to 4. Subrankings (2A, 2B, etc.) are also used. Other Information:
liquid or up to a temperature at which the sample being tested shows an obvious BEI - ACGIH Biological Exposure Indices, represent the levels of determinants which are
physical change. Combustible pellets with a representative diameter of greater than 2 most likely to be observed in specimens collected from a healthy worker who has been mm (10 mesh). Solids containing greater than 0.5 percent by weight of a flammable or exposed to chemicals to the same extent as a worker with inhalation exposure to the combustible solvent are rated by the closed up flash point of the solvent. Most ordinary combustible materials. 2 Materials that must be moderately heated or exposed to
ECOLOGICAL INFORMATION:
relatively high ambient temperatures before ignition can occur. Materials in this EC is the effect concentration in water. BCF = Bioconcentration Factor, which is used to
degree would not under normal conditions form hazardous atmospheres with air, but determine if a substance will concentrate in lifeforms which consume contaminated plant under high ambient temperatures or under moderate heating could release vapor in or animal matter. TL
sufficient quantities to produce hazardous atmospheres with air: Liquids having a m = median threshold limit; Coefficient of Oil/Water Distribution is
represented by log K
flash point at or above 37.8°C (100°F) and below 93.4°C (200°F) (i.e. Class II and ow or log Koc and is used to assess a substance’s behavior in
Class IIIA liquids.) Solid materials in the form of powders or coarse dusts of representative diameter between 420 microns (40 mesh) and 2 mm (10 mesh) that REGULATORY INFORMATION:
burn rapidly but that generally do not form explosive mixtures in air. Solid materials U.S. and CANADA:
in fibrous or shredded form that burn rapidly and create flash fire hazards, such as ACGIH: American Conference of Governmental Industrial Hygienists, a professional
cotton, sisal and hemp. Solids and semisolids that readily give off flammable vapors. association which establishes exposure limits. Solids containing greater than 0.5 percent by weight of a flammable or combustible This section explains the impact of various laws and regulations on the material. EPA is
solvent are rated by the closed cup flash point of the solvent. 3 Liquids and solids
the U.S. Environmental Protection Agency. NIOSH is the National Institute of
that can be ignited under almost all ambient temperature conditions. Materials in this Occupational Safety and Health, which is the research arm of the U.S. Occupational
degree produce hazardous atmospheres with air under almost all ambient Safety and Health Administration (OSHA). WHMIS is the Canadian Workplace
temperatures or, though unaffected by ambient temperatures, are readily ignited Hazardous Materials Information System. DOT and TC are the U.S. Department of
under almost all conditions: Liquids having a flash point below 22.8°C (73°F) and Transportation and the Transport Canada, respectively. Superfund Amendments and having a boiling point at or above 37.8°C (100°F) and those liquids having a flash Reauthorization Act (SARA); the Canadian Domestic/Non-Domestic Substances List
point at or above 22.8°C (73°F) and below 37.8°C (73°F) and below 37.8°C (100°F) (DSL/NDSL); the U.S. Toxic Substance Control Act (TSCA); Marine Pollutant status
(i.e. Class IB and IC liquids). Materials that, on account of their physical form or according to the DOT; the Comprehensive Environmental Response, Compensation,
environmental conditions, can form explosive mixtures with air and are readily and Liability Act (CERCLA or Superfund); and various state regulations. This section
also includes information on the precautionary warnings which appear on the material’s
package label. OSHA - U.S. Occupational Safety and Health Administration.
H3R Clean Agent Specialists, Inc.
Halon 1211
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Source: http://www.tepi.co/userfiles/halotron%20grande.pdf