MATERIAL SAFETY DATA SHEET FILE NUMBER: 1902 NAME OF PRODUCT RECLAMITE DATE PREPARED: 8/13/04 SECTION 1: PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: RECLAMITE HAZARDOUS MATERIALS IDENTIFICATION SYSTEM SYNONYMS: PETROLEUM EMULSION HMIS® HAZARD RATING PRODUCT CODES: 4 - SEVERE HEALTH 1 * MANUFACTURER: TRICOR REFINING, LLC 3 - SERIOUS FLAMMABILITY 0 DIVISION: BAKERSFIELD 2 - MODERATE REACTIVITY 0 ADDRESS: P.O. BOX 5877, BAKERSFIELD, CA 1 - SLIGHT EMERGENCY PHONE: (661) 393-7110 0 - MINIMAL PREPARED BY: TRICOR REFINING, LLC HEALTH, SAFETY AND ENVIRONMENTAL DEPARTMENT SECTION 2: HAZARDOUS INGREDIENTS / IDENTITY INFORMATION CHEMICAL FAMILY: PETROLEUM HYDROCARBON IN WATER EMULSION HAZARDOUS CAL-OSHA ACGIH TLV COMPONENT(S) RECOMMENDED
CAS No. 64742-34-3 Heavy Naphthenic Distillate
SECTION 3: HEALTH HAZARDS IDENTIFICATION ROUTES OF ENTRY: EYES: Yes SKIN: Yes INGESTION: Yes INHALATION: Yes HEALTH HAZARDS (ACUTE AND CHRONIC):
The cool material is not expected to cause eye irritation.
The cool material is not expected to cause skin irritation.
INGESTION:
This product is not expected to be acutely toxic by ingestion. If swallowed, do not induce vomiting, call a physician.
INHALATION:
Remove the person to fresh air if respiratory discomfort occurs.
SIGNS AND SYMPTOMS OF EXPOSURE: EYES:
Prolonged exposure may cause dermatitis.
INGESTION:
Overexposure may cause dizziness, drowsiness, headache and nausea.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE:
Persons with preexisting skin or respiratory disorders may have their conditions aggravated by overexposure to this material.
CARCINOGENICITY:
ACGIH, NTP, OSHA and IARC carcinogen lists were checked for those components with CAS Registry Numbers (64742-34-3) and (64742-11-6).
This product is not listed as carcinogenic.
Group 2B – This product is possibly carcinogenic to humans. This product contains petroleum oils similar to ones categorized by the International Agency for Research on Cancer as causing skin cancer in laboratory animals when the oil was repeatedly applied for most of the lifetime of the animal with no effort made to remove the oil between applications. Handling instructions and precautions outlined in this MSDS should be followed when handling this product.
This product contains no ingredients classified as carcinogens.
This product contains no ingredients classified as carcinogens.
CA PROP 65:
This product contains chemicals in trace quantities that are on the California Proposition 65 List.
SECTION 4: EMERGENCY AND FIRST AID MEASURES
Immediately flush eyes with water for a minimum of 15 minutes. Seek medical attention
immediately. SKIN:
Wash contact areas with soap and water. Remove and clean oil soaked clothing daily and wash affected area.
INGESTION:
Do not induce vomiting. If operating conditions create airborne concentrations that exceed the exposure standard, the use of an approved NIOSH/OSHA respirator for organic vapors or air-supplied breathing equipment is recommended. If ingested, seek medical attention.
INHALATION:
Not expected to be a problem. However, if respiratory irritation, dizziness, nausea or unconsciousness occurs due to excessive vapor or mist exposure, seek medical attention. If operating conditions create airborne concentrations that exceed the exposure standard, the use of an approved NIOSH/OSHA respirator for organic vapors or air-supplied breathing equipment is recommended.
SECTION 5: FIRE AND EXPLOSION HAZARD DATA FLAMMABLE LIMITS IN AIR, (% BY VOLUME) FLASH POINT: COC ºF: EXTINGUISHING MEDIA: SPECIAL FIRE FIGHTING PROCEDURES: Do not enter confined fire space without proper protective equipment
including self-contained breathing apparatus. See Hazardous Decomposition Products.
HAZARDOUS DECOMPOSITION PRODUCTS:
Normal combustion forms carbon dioxide and water vapor, and may
produce oxides of sulfur and nitrogen. Incomplete combustion can
SECTION 6: SPILL OR LEAK PROCEDURES ACCIDENTAL RELEASE MEASURES:
In case of spill, clean up using absorbent material such as earth or
sand. WASTE DISPOSAL METHOD:
Observe Federal, State and Local regulations covering chemical waste
spills. RCRA HAZARD CLASS:
This product is not a characteristic hazardous waste under RCRA. No
EPA waste numbers are applicable for this product’s components.
SECTION 7: HANDLING AND STORAGE HANDLING AND STORAGE:
Avoid fire, sparks or open flame. Wear appropriate personal protective
equipment to ensure that this product does not contact the eyes or skin.
VENTILATION:
Use adequate ventilation to keep the airborne concentrations of this material below the established exposure limits.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION RESPIRATORY PROTECTION:
If operating conditions create airborne concentrations that exceed the exposure standard for mineral oil mists, the use of an approved NIOSH/OSHA respirator for organic vapors or air supplied breathing equipment is recommended.
EYE PROTECTION:
Wear appropriate safety glasses, goggles or face shield.
SKIN PROTECTION:
Long sleeve cotton shirt and cotton pants are recommended. Wear appropriate gloves.
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE: PHYSICAL STATE: INITIAL BOILING POINT: VAPOR PRESSURE (mmHg): PERCENT VOLATILE (% BY VOL.): VAPOR DENSITY (AIR = 1): EVAPORATION RATE (WATER = 1): SPECIFIC GRAVITY (H2O = 1): SOLUBILITY SECTION 10: REACTIVITY DATA STABILITY: CONDITIONS CONTRIBUTING TO INSTABILITY: INCOMPATIBILITY (MATERIAL TO AVOID): HAZARDOUS DECOMPOSITION OR BY-PRODUCTS:
Normal combustion forms carbon dioxide and water vapor,
and may produce oxides of sulfur and nitrogen. Incomplete
HAZARDOUS POLYMERIZATION: SECTION 11: TRANSPORT INFORMATION U.S. DEPARTMENT OF TRANSPORTATION:
Not regulated as a hazardous material for transportation.
SECTION 12: REGULATORY INFORMATION U.S. FEDERAL REGULATIONS: TSCA (TOXIC SUBSTANCE CONTROL ACT) REGISTRY: CERCLA (COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPENSATION AND LIABILITY ACT): Petroleum emulsions are not hazardous substances under CERCLA. SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT): Section 302/304:
Petroleum emulsions are not a hazardous chemical in 40 CFR Part 355 and are not known to contain an extremely hazardous substance in a concentration greater than one percent by weight.
Section 311/312: Section 313:
This product is not known to contain any components in concentrations above de minimus levels that are listed as toxic in 40 CFR Part 372 pursuant to the requirements of Section 313 of SARA.
29 CFR 1910.1200 (Hazard Communication) required
STATE REGULATIONS:
Mineral oil, petroleum extracts, heavy naphthenic distillate solvent appears on one or more of the hazardous substances lists in the following states:
The information provided in this Material Safety Data Sheet is believed to be accurate and reliable on and as of the date on page one. However, this Material Safety Data Sheet is not a guarantee or warranty of any kind, express or implied. Any and all warranties of merchantability and/or fitness for a particular purpose are specifically disclaimed. It is the user’s responsibility to determine the conditions under which the product is used, including the selection of engineering controls, work practices and Personal Protective Equipment to minimize hazards.
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