Safety data sheet

SIGMA-ALDRICH
sigma-aldrich.com
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006 GENERIC EU MSDS - NO COUNTRY SPECIFIC DATA - NO OEL DATA IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
Product identifiers
Product name
Relevant identified uses of the substance or mixture and uses advised against
: Laboratory chemicals, Manufacture of substances Details of the supplier of the safety data sheet
1 Science Park Road #02-14 The Capricorn Singapore Science Park Road II SINGAPORE 117528 SINGAPORE Emergency telephone number
HAZARDS IDENTIFICATION
Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008 [EU-GHS/CLP]
Organic peroxides (Type C)
Eye irritation (Category 2)
Skin sensitization (Category 1)
Classification according to EU Directives 67/548/EEC or 1999/45/EC
Explosive when dry. May cause fire. Irritating to eyes. May cause sensitization by skin contact.
Label elements
Labelling according Regulation (EC) No 1272/2008 [CLP]
Pictogram
Keep/Store away from clothing/ combustible materials. Wear protective gloves/ protective clothing/ eye protection/ face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove Aldrich - 517909
contact lenses, if present and easy to do. Continue rinsing. Store at temperatures not exceeding 30°C/ 86 °F. Keep cool. Supplemental Hazard information (EU) EUH001
According to European Directive 67/548/EEC as amended.
Hazard symbol(s)
May cause sensitization by skin contact. Keep away from easily oxidizable materials. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. This material and its container must be disposed of in a safe way. Wear suitable protective clothing, gloves and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Keep at temperature not exceeding 30 °C. Other hazards - none
COMPOSITION/INFORMATION ON INGREDIENTS
Mixtures
Synonyms
Benzoyl peroxide
Org. Perox. B; Eye Irrit. 2; Skin 50 - 100 % For the full text of the H-Statements and R-Phrases mentioned in this Section, see Section 16 FIRST AID MEASURES
Description of first aid measures
General advice
Consult a physician. Show this safety data sheet to the doctor in attendance.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
In case of skin contact
Wash off with soap and plenty of water. Consult a physician.
In case of eye contact
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
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If swallowed
Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.
Most important symptoms and effects, both acute and delayed
To the best of our knowledge, the chemical, physical, and toxicological properties have not been
thoroughly investigated.
Indication of any immediate medical attention and special treatment needed
no data available
FIREFIGHTING MEASURES
Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special hazards arising from the substance or mixture
Carbon oxides
Advice for firefighters
Wear self contained breathing apparatus for fire fighting if necessary.
Further information
Use water spray to cool unopened containers.
ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Avoid dust formation. Avoid breathing vapors, mist or gas. Ensure
adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust.
Environmental precautions
Prevent further leakage or spillage if safe to do so. Do not let product enter drains.
Methods and materials for containment and cleaning up
Sweep up and shovel. Contain spillage, and then collect with an electrically protected vacuum cleaner or
by wet-brushing and place in container for disposal according to local regulations (see section 13). Keep
in suitable, closed containers for disposal. Contain spillage, pick up with an electrically protected vacuum
cleaner or by wet-brushing and transfer to a container for disposal according to local regulations (see
section 13).
Reference to other sections
For disposal see section 13.
HANDLING AND STORAGE
Precautions for safe handling
Avoid contact with skin and eyes. Avoid formation of dust and aerosols.
Provide appropriate exhaust ventilation at places where dust is formed.Keep away from sources of ignition
- No smoking.Keep away from heat and sources of ignition.
Conditions for safe storage, including any incompatibilities
Store in original container. Keep container tightly closed in a dry and well-ventilated place. Store in cool
place.
Specific end use(s)
no data available
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EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Components with workplace control parameters
Exposure controls
Appropriate engineering controls
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and
at the end of workday.
Personal protective equipment
Eye/face protection
Face shield and safety glasses Use equipment for eye protection tested and approved under
appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin protection
The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and
the standard EN 374 derived from it.
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands.
Body Protection
Complete suit protecting against chemicals, The type of protective equipment must be selected
according to the concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection
Where risk assessment shows air-purifying respirators are appropriate use a full-face particle
respirator type N100 (US) or type P3 (EN 143) respirator cartridges as a backup to engineering
controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use
respirators and components tested and approved under appropriate government standards such
as NIOSH (US) or CEN (EU).
PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
Flammability (solid, gas) no data available Aldrich - 517909
Other safety information
no data available
STABILITY AND REACTIVITY
10.1 Reactivity
10.2 Chemical stability
10.3 Possibility of hazardous reactions
10.4 Conditions to avoid
10.5 Incompatible materials
10.6 Hazardous decomposition products
Other decomposition products - no data available TOXICOLOGICAL INFORMATION
11.1 Information on toxicological effects
Acute toxicity
no data available
Skin corrosion/irritation
no data available
Serious eye damage/eye irritation
no data available
Respiratory or skin sensitization
no data available
Germ cell mutagenicity
no data available
Carcinogenicity
3 - Group 3: Not classifiable as to its carcinogenicity to humans (Benzoyl peroxide) Reproductive toxicity
no data available
Specific target organ toxicity - single exposure
no data available
Specific target organ toxicity - repeated exposure
no data available
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Aspiration hazard
no data available
Potential health effects
Inhalation
May be harmful if inhaled. May cause respiratory tract irritation. Ingestion
May be harmful if absorbed through skin. May cause skin irritation. Signs and Symptoms of Exposure
To the best of our knowledge, the chemical, physical, and toxicological properties have not been
thoroughly investigated.
Additional Information
RTECS: Not available
ECOLOGICAL INFORMATION
12.1 Toxicity
12.2 Persistence and degradability
12.3 Bioaccumulative potential
12.4 Mobility in soil
12.5 Results of PBT and vPvB assessment
12.6 Other adverse effects
DISPOSAL CONSIDERATIONS
13.1 Waste treatment methods
Product
Burn in a chemical incinerator equipped with an afterburner and scrubber but exert extra care in igniting
as this material is highly flammable. Offer surplus and non-recyclable solutions to a licensed disposal
company.
Contaminated packaging
Dispose of as unused product.
TRANSPORT INFORMATION
14.1 UN number
14.2 UN proper shipping name
ADR/RID: ORGANIC PEROXIDE TYPE C, SOLID (DIBENZOYL PEROXIDE) (Benzoyl peroxide) IMDG: ORGANIC PEROXIDE TYPE C, SOLID (DIBENZOYL PEROXIDE) (Benzoyl peroxide) Organic peroxide type C, solid (Dibenzoyl peroxide) (Benzoyl peroxide) Special Provisions: “Keep away from heat” label required. 14.3 Transport hazard class(es)
14.4 Packaging group
14.5 Environmental hazards
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14.6 Special precautions for user
REGULATORY INFORMATION
This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006. 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.2 Chemical Safety Assessment
OTHER INFORMATION
Text of H-code(s) and R-phrase(s) mentioned in Section 3
Extreme risk of explosion by shock, friction, fire or other sources of ignition. May cause sensitization by skin contact. Further information
Copyright 2012 Sigma-Aldrich Co. LLC. License granted to make unlimited paper copies for internal use
only.
The above information is believed to be correct but does not purport to be all inclusive and shall be
used only as a guide. The information in this document is based on the present state of our knowledge
and is applicable to the product with regard to appropriate safety precautions. It does not represent any
guarantee of the properties of the product. Sigma-Aldrich Corporation and its Affiliates shall not be held
liable for any damage resulting from handling or from contact with the above product. See www.sigma-
aldrich.com and/or the reverse side of invoice or packing slip for additional terms and conditions of sale.
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